BKLTX - UNLEADED GASOLINE

Product Identification

Product ID:UNLEADED GASOLINE
MSDS Date:03/05/1992
FSC:9130
NIIN:00-148-7103
MSDS Number: BKLTX

Responsible Party
COASTAL EAGLE POINT OIL CO
9 GREENWAY PLAZA
HOUSTON, TX 77046
US

Emergency Phone: 713-877-1400

Info Phone: 713-877-1400

Preparer: DELNO D. MALZAHN, CIH

Cage: 0BDU2

Contractor
COASTAL EAGLE POINT OIL CO, THE COSTAL CORP.
HOUSTON, TX 77046 US

Telephone: 713-877-1400

Cage: 0BDU2

Ingredients

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192


BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0-5.0%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS


ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0.0-5.0%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS


XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS


HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <3.5%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


HEXANE ISOMERS ( OTHER THAN N-HEXANE )

Fraction By Weight: <9.0%

OSHA PEL 500 PPM

ACGIH TLV: 500 PPM


1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0.0-5.0%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192


TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0.0-25%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS


CUMENE (SARA III)

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: 2.0%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 50 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS


BUTANE

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: <9.0%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM; 9192


PENTANE

CAS: 109-66-0

RTECS: RZ9450000

Fraction By Weight: <6.5%

OSHA PEL 1000 PPM/750 STEL

ACGIH TLV: 600 PPM/750STEL;9293


TERT-BUTYL ALCOHOL (SARA III)

CAS: 75-65-0

RTECS: EO1925000

Fraction By Weight: 0-10%

OSHA PEL 100 PPM

ACGIH TLV: 100PPM 9394


METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Hazards

LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATION, CENTRAL NERVOUS
SYSTEM EFFECTS. GASOLINE IF SWALLOWED MAY MAY BE ASPIRATED INTO THE
LUNGS RESULTING IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS.
CHRONIC: BENZENE IS A CONFIRMED CARC INOGEN WHICH DESTROYS BLOOD
FORMING ORGANS. PROLONGED EXPOSURE RESULTS IN LIVER AND KIDNEY
DAMAGE IN RATS AND MICE.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES/SKIN: SLIGHT IRRITATION. INHALATION:
HEADACHE, NAUSEA, WEAKNESS, SEDATION AND UNCONSCIOUSNESS.
INGESTION: IRRITATION TO THE INTESTINES. ASPIRATION INTO THE LUNGS
AFTER INGESTION MAY RESULT IN PUL MONARY EDEMA AND CHEMICAL
PNEUMONITIS.
Medical Cond Aggravated by Exposure:EITHER CONCENTRATED OR DILUTE FORMS
OF THIS PRODUCT AT TLV(OR EVEN BELOW) MAY AGGRAVATE EXISTING
DERMATITIS OR RESPIRATORY DISORDERS. BENZENE DEGENERATES BLOOD
PRODUCING ORGANS LEADING TO LEUKEMIA.

First Aid

First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND
WATER. INHALATION: REMOVE TO FRESH AIR. FOR RESPIRATORY DISTRESS,
GIVE AIR , OXYGEN OR CPR IF NECESSARY. INGESTION:DO NOT INDUCE
VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS TO PREVENT
ASPIRATION INTO LUNGS. GET MEDICAL ATTENTION IF REQUIRED IN ALL
CASES.

Fire Fighting

Flash Point Method:TCC
Flash Point:=-42.8C, -45.F
Autoignition Temp:=257.2C, 495.F
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
Fire Fighting Procedures:TRY TO SMOTHER FIRE. A DIRECT WATER STREAM
WILL SPREAD IT. SPRAY WATER TO COOL CONTAINERS EXPOSED TO A FIRE.
FIREFIGHTERS SHOULD WEAR SCBA AND FIRE CLOTHING.
Unusual Fire/Explosion Hazard:FLOWING GASOLINE CAN BE IGNITED BY
SELF-GENERATED STATIC ELECTRICITY. RUNOFF INTO A SEWER CNA CREAATE
A FIRE OR EXPLOSION HAZARD WELL DOWNSTREAM FROM THE SOURCE

Accidental Release

Spill Release Procedures:REMOVE SOURCES OF COMBUSTION (INCLUDING
ENGINES, POWER TOOLS). CLEAN UP SPILL. DO NOT FLUSH DOWN SEWER OR
TO SURFACE WATER. VENTILATE AREA AND AVOID BREATHING VAPORS OR
MISTS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling

Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
A COOL PLACE. GROUND AND BOND ALL STORAGE CONTAINERS AGAINST
STATIC. EMPTY CONTAINERS MAY BE DANGEROUS.
Other Precautions:USE ONLY AS A MOTOR FUEL. NEVER AS A CLEANING SOLVENT
OR DEGREASER. USE EXPLOSION PROOF ELECTRICAL EQUIPMENT. DO NOT
SMOKE IN AREA.

Exposure Controls

Respiratory Protection:A NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR,
SUPPLIED AIR OR SELF-CONTAINED BREATHING APPARATUS MUST BE USED
WHEN VAPOR CONCENTRATIONS EXCEED THE OCCUPATIONAL EXPOSURE LIMITS.
Ventilation:USE ADEQUATE VENTILATION TO KEEP VAPOR CONCCENTRATIONS OF
THIS MATERIAL BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:WEAR OIL IMPERVIOUS (EG: NITRILE) GLOVES
Eye Protection:SAFETY GOGGLES. REMOVE CONTACT LENSES.
Other Protective Equipment:OIL IMPERVIOUS INDUSTRIAL WORK CLOTHING TO
MINIMIZE SKIN CONTACT. EYE BATH AND SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. USE WATERLESS HAND
CLEANER TO WASH EXPOSED SKIN. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
THE VARIABLE COMPOSITION MAKES IT IMPOSSIBLE TO SET SPECIFIC EXPOSURE
LIMIT FOR ALL COMPOSTIONS OF THIS MATERIAL. SPECIFIC EXPOSURE
LIMITS FOR POTENTIAL COMPONENTS SUCH AS BENZENE SHOULD BE APPLIED
BA SED ON AIR MONITIORING TO ASSURE EMPLOYEES ARE NOT EXPOSED TO
EXCESSIVE VAPOR LEVELS OF COMPONENTS.

Chemical Properties

HCC:F1
Boiling Pt:=26.7C, 80.F
Vapor Pres:325-525HG
Vapor Density:3-4
Spec Gravity:0.7 - 0.77
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE FLUID, AROMATIC ODOR
Percent Volatiles by Volume:100 %

Stability

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS AND ALKALIES, HALOGENS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION, SUCH AS STATIC ELECTRICITY.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
HYDROCARBONS.

Disposal

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.